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IRMPD-based quantification of ER-catalyzed saturation and cyclopropanation reactions

External protocol Created on 30 Apr 2014

Authors

Liangcai Gu, Bo Wang, David Sherman, and Kristina Håkansson

Summary

The quantification of enzyme reactions with protein-linked substrates and products is highly challenging. Here we report a facile technique that allowed us to precisely quantify ratios of ACP-linked species in the ER-catalyzed saturation and cyclopropanation reactions by using the IRMPD-based method (Figure 1). This technique has wide application in natural product biosynthesis studies.

Further details

The protocol was published on Protocol Exchange on 9 June 2009. To see the entire protocol, click on the source link.

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