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Spin-state modulation by host-guest chemistry with cucurbiturils.

Created on 22 Apr 2025

Authors

Ke Lu, Yu-Xiao Chen, Jie-Sheng Hu, Zhi-Kun Liu, Xin-Li Shi, Meng Yu, Alyona A Starikova, Jun Tao

Published in

Chemical communications (Cambridge, England). Apr 22, 2025. Epub Apr 22, 2025.

Abstract

The host-guest binding of cucurbit[7]uril to a methylpyridinium-functionalized Co(II)-terpyridine complex shifts the spin equilibrium to the low-spin state (ΔT1/2 = 77 K) via secondary coordination sphere perturbations.

PMID:
40260474
Bibliographic data and abstract were imported from PubMed on 22 Apr 2025.

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