Gold/Copper Dual-Catalyzed Annulation of Arynes with Phosphites: A Synthetic Strategy for Dibenzophospholes.

Authors

Donghwa Shin, Seo-Jung Han

Published in

Organic letters. Apr 27, 2025. Epub Apr 27, 2025.

Abstract

A synthetic approach to dibenzophospholes was developed via the gold- and copper-catalyzed annulation reactions of arynes and phosphites. The reaction conditions demonstrated a broad functional group tolerance, enabling the synthesis of a diverse range of dibenzophosphole 5-oxides. This method is useful for preparing dibenzophospholes with unique optical and electronic properties.

PMID:
40287836
Bibliographic data and abstract were imported from PubMed on 27 Apr 2025.

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