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Rational design of N-heterocyclic COF-based photocatalysts: synergistic metal-ligand coordination for efficient H2O2 production.

Created on 19 May 2025

Authors

Nuonan Mu, Ze Luo, Wei Shan, Haibo Huang, Hua Tang

Published in

Chemical communications (Cambridge, England). May 19, 2025. Epub May 19, 2025.

Abstract

This study successfully constructed a Cd-COF with an N-Cd coordination structure via a one-step solvothermal method and demonstrated its application in photocatalytic H2O2 production. The N-Cd coordination structure not only exhibits exceptional adsorption capacity for oxygen molecules, but also acts as an active center to provide electrons for the reduction reaction, thereby significantly accelerating the efficient generation of H2O2. Experimental results reveal that the N-Cd coordination structure optimizes the electronic structure and regulates the local microenvironment, leading to high-efficiency utilization of photogenerated electrons.

PMID:
40384419
Bibliographic data and abstract were imported from PubMed on 19 May 2025.

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