Siliconizing-Driven Layer-by-Layer Growth of 2D Tellurides with Controlled Crystallization.

Authors

Weitao Liu, Qinghe Wang, Yuanyuan Zhao, Can Liu, Yunrou Wu, Jinpei Zhao, Zhaolong Chen, Yuan Yin, Feng Yang, Peng Gao, Kaihui Liu, Mingju Huang, Feng Ding, Ke Chen

Published in

Advanced materials (Deerfield Beach, Fla.). Pages e2501451. Jun 03, 2025. Epub Jun 03, 2025.

Abstract

2D transition metal tellurides (TMTs) possess fascinating properties for applications in ferroelectrics and optoelectronics. Nevertheless, it is still challenging to grow high-quality 2D TMTs with the desired phase (especially high-temperature phase) because of the weak bonding between the transition metal and Te as compared to S and Se atoms. Here, a strategy of siliconizing-driven layer-by-layer growth is reported to synthesize 2D ZrTe₂ and ZrTe₃ crystals with high crystallinity and desired thickness. Both as-synthesized crystals exhibit large-area uniform phases and atomically precise layered stacking structures. 2D ZrTe₂ shows type-II Weyl semimetal characteristics with negative magnetoresistance, and 2D ZrTe₃ demonstrates the existence of charge density waves and intrinsic superconductivity. Theoretical study reveals that silicon atoms can infiltrate and isolate a single layer of zirconium atoms and allow them to be tellurized in a layer-by-layer manner. The work paves the way for the synthesis of layer-controlled 2D TMTs and lays a material foundation for their physical property research.

PMID:
40459504
Bibliographic data and abstract were imported from PubMed on 03 Jun 2025.

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