A Heptagon-Embedded Structural Isomer of Azacorannulene.

Authors

Yude Ji, Zikang Ma, Lin Wan, Weifan Wang, Gang Zhang

Published in

Organic letters. Jul 15, 2025. Epub Jul 15, 2025.

Abstract

A nitrogen-doped heptagon-embedded bowl-shaped molecule that can be viewed as a structural isomer of azacorannulene was synthesized and characterized. The presence of a seven-membered ring significantly alters the molecular electronic structure and results in a distinct optical property. The pyramidalized geometry of nitrogen is crucial for releasing the molecular strain as well as rendering the fused pentagonal rings aromaticity to enhance the molecular stability.

PMID:
40662218
Bibliographic data and abstract were imported from PubMed on 15 Jul 2025.

Read full publication at:
Please sign in to see all details.

Stats

1-terrible, 9-excellent. How would you rate this publication? Sign in in to submit your rating.

Post a comment

You need to be signed in to post comments. You can sign in here.

Comments

There are no comments yet.