Stereoselective Syntheses of Cyclic Microsclerodermin Derivatives.

Authors

Kevin Bauer, Uli Kazmaier

Published in

Chemistry (Weinheim an der Bergstrasse, Germany). Pages e02459. Sep 26, 2025. Epub Sep 26, 2025.

Abstract

Starting from l-xylose and d-arabinose, six different cyclic microscleroderma derivatives were successfully obtained. Key steps of the syntheses are, on the one hand, Sakurai allylations, whose stereochemical course depends on the Lewis acid used, and on the other hand, photochemical Wolff rearrangements in the presence of complex aminofuranosides. Finally, aromatic side chains were introduced via cross metathesis.

PMID:
41013931
Bibliographic data and abstract were imported from PubMed on 27 Sep 2025.

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