Multifunctional carbon-modified MoS₂ with expanded interlayer spacing and multiple exposed sulfur active sites for high-capacity Hg(ii) adsorption.

Authors

Mingmin Bai, Wenyuan Guo, Yiyang Zhang, Ruiqiang Yang, Weixin Li

Published in

RSC advances. Volume 15. Issue 45. Pages 38069-38081. Oct 08, 2025. Epub Oct 13, 2025.

Abstract

A novel multifunctional carbon-modified MoS₂ material (C-W-D-MoS₂-x) was synthesized through a solvothermal method, exhibiting expanded interlayer spacing, a large surface area (∼47.03 m² g^-1), and abundant exposed sulfur (S) active sites that enabled efficient adsorption of Hg²⁺ from wastewater. Among the prepared variants, C-W-D-MoS₂-0.03 showed the highest adsorption performance, achieving an exceptional distribution coefficient (K _d ) of 2.0 × 10⁵ mL g^-1. The adsorption kinetics were best described by the pseudo-second-order model, while the adsorption isotherms were well-fitted to the Langmuir model, with a maximum adsorption capacity (q _m ) of 1974.0 mg g^-1. This remarkable adsorption capability of C-W-D-MoS₂-0.03 can be attributed to the synergistic effect of carbon functional groups and the high density of S active sites. Furthermore, an alumina inorganic membrane functionalized with C-W-D-MoS₂-0.03 was successfully assembled into a device, demonstrating a dynamic removal process that reduced 50 mg L^-1 of Hg²⁺ to below 0.1 mg L^-1.

PMID:
41090179
Bibliographic data and abstract were imported from PubMed on 15 Oct 2025.

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