2M Phase Engineering of W_1-xMo_xS₂ Alloy Nanosheets for Enhanced Catalytic Hydrogen Evolution Reaction.

Authors

Ju Yeon Kim, Youn Jun Choi, In Hye Kwak, Seo Yun Jeong, Junaid Ihsan, Irtiqa Mishal, Jun Hyeok Choi, Ik Seon Kwon, Hong Seok Kang, Jeunghee Park

Published in

Small (Weinheim an der Bergstrasse, Germany). Pages e74226. Jun 19, 2026. Epub Jun 19, 2026.

Abstract

The phase engineering of two-dimensional transition-metal dichalcogenides (TMDs) remains difficult yet crucial for both fundamental studies and practical applications. In this work, WS₂-MoS₂ (W_{1- x}Mo_xS₂) alloy nanosheets with tunable crystal structures (2H, 2 M, and 1T') were prepared via a colloidal synthesis conducted at 220-300°C. Interestingly, 2 M → 2H phase transition temperature was higher for WS₂ than for MoS₂ (e.g., 300°C vs. 260°C), indicating that WS₂ possesses a more stable metastable phase. W-rich alloying was found to stabilize further the metastable structure of 2 M phase. First-principles calculations consistently revealed that alloying, NH₄ ⁺ intercalation, and sulfur/metal vacancies all contribute to enhancing the stability of the metastable phases. In acidic media, the W-rich alloy nanosheets exhibited improved hydrogen evolution reaction (HER) activity, which is likely associated with their 2 M phase. The calculations also suggested that the 2 M phase alloys effectively activate the basal S atoms toward HER, offering valuable insight into how alloying modulates the catalytic properties of TMD-based electrocatalysts.

PMID:
42318754
Bibliographic data and abstract were imported from PubMed on 19 Jun 2026.

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