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Hydrosilylation of ω-hydroxyalkenes catalysed with 2-methacryloyloxyethyl-phosphorylcholine-protected ruthenium nanoparticles.

Created on 22 Jun 2026

Authors

Mana Yamamoto, Yuuki Tanioka, Sakiko Miyamoto, Mizuho Fujisawa, Tatsuki Nagata, Yuki Kimura, Kazuki Tabaru, Honami Iguchi, Takeyuki Suzuki, Takashi Toyao, Zen Maeno, Ken-Ichi Shimizu, Takeshi Watanabe, Yasuhiko Iwasaki, Yasushi Obora

Published in

Chemical communications (Cambridge, England). Jun 22, 2026. Epub Jun 22, 2026.

Abstract

Selective hydrosilylation of ω-hydroxyalkenes is achieved using 2-methacryloyloxyethyl phosphorylcholine (MPC)-protected ruthenium nanoparticles ((PC-SH) Ru NPs). The MPC-derived surface suppresses O-silylation, enabling unprecedented CC functionalisation unattainable with other Ru catalysts.

PMID:
42325007
Bibliographic data and abstract were imported from PubMed on 22 Jun 2026.

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