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The first structurally characterized coordination compounds with homocysteine.

Created on 02 Jul 2026

Authors

Masahiro Kouno, Takumi Konno, Naoto Kuwamura, Tatsuhiro Kojima, Shota Takamuku, Soichiro Nishio, Nobuto Yoshinari

Published in

Chemical communications (Cambridge, England). Jul 02, 2026. Epub Jul 02, 2026.

Abstract

D-Homocysteine (D-H2hcys) coordinates to CoIII center in a tridentate-N,O,S mode to form trans(N)-[Co(D-hcys)2]-, which binds to PdII center to produce an S-bridged CoIII2PdII complex with two trans(N)-[Co(D-hcys)2]- units. The use of racemic D/L-H2hcys leads to the selective isolation of an analogous CoIII2PdII complex with trans(N)-[Co(D-hcys)2]- and trans(N)-[Co(L-hcys)2]- units.

PMID:
42389800
Bibliographic data and abstract were imported from PubMed on 02 Jul 2026.

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