Photocatalytic Decarboxylative Coupling of Diacyl Peroxides with TEMPO.

Authors

Jiabin Shen, Xiangbo Ma, Guili Jian, Hao Xu, Chao Shen

Published in

The Journal of organic chemistry. Jul 07, 2026. Epub Jul 07, 2026.

Abstract

The facile construction of C(sp³)-O bonds plays a critically important role in organic synthesis. Herein, we report a visible-light-mediated decarboxylative C(sp³)-O bond formation reaction under metal- and base- and additive-free conditions with irradiation. This protocol is characterized by its broad substrate compatibility and operational simplicity. Meanwhile, the potential applications of this operationally simple and general methodology in synthetic chemistry have been demonstrated by the late-stage functionalization of bioactive molecules and subsequent modifications of TEMPO derivatives.

PMID:
42411299
Bibliographic data and abstract were imported from PubMed on 07 Jul 2026.

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