Authors
S Altun, E Karaca, M Tuncer, E Erdem, H Göçmez
Published in
ACS omega. Volume 11. Issue 26. Pages 38440-38449. Jul 07, 2026. Epub Jun 20, 2026.
Abstract
This study reports the synthesis and electrochemical evaluation of gel-synthesized ZrB2 for all-solid-state symmetric supercapacitors. The prepared ZrB2 powders were characterized using XRD, SEM, FTIR, and XPS analyses. Electrochemical performance was tested using cyclic voltammetry (CV) in 1 M Na2SO4 electrolyte in both positive and negative voltage ranges at a wide range of scan rates from 5 to 500 mV/s. Specific capacitances ranged from 18 to 55 F/g in the positive region and 19-73 F/g in the negative region. Dunn's method analysis revealed that pseudocapacitive contributions dominated at low scan rates (80%), while electric double-layer capacitance (EDLC) contributions dominated at high scan rates (70%), indicating hybrid energy storage behavior. A solid-state symmetric supercapacitor cell was assembled using ZrB2 electrodes with PVA/Na2SO4 gel electrolyte, exhibiting a low internal resistance of 2.79 Ω·cm2 and an operational voltage of 1.4 V with rectangular CV profiles. Galvanostatic charge-discharge (GCD) tests showed an energy density of 5.0 Wh/kg and a power density of 5600 W/kg at 8 mA cm-2. The cell exhibited good cyclic stability of 90.7% after 5000 cycles. Additionally, a gel-derived ZrB2 electrode was successfully applied in a solid-state zinc-ion hybrid supercapacitor configuration, demonstrating a high specific capacity of 230 mAh/g at 0.9 C and excellent reversibility with 87% Coulombic efficiency. These results confirm the versatility of gel-synthesized ZrB2 for both symmetric and hybrid energy storage systems, making it a promising electrode material for multifunctional solid-state devices.
PMID:
42428854
Bibliographic data and abstract were imported from PubMed on 10 Jul 2026.
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