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Construction of a multifunctional Cu-HHTP/FeO(OH) heterojunction for high-performance photocatalysis and Li-ion batteries.

Created on 16 Jul 2026

Authors

Yang Han, Fuyan Zhao, Xinyue Luo, Xin Chen, Weihao Li, Junhao Tang, Bingquan Liu, Ziyan Wang, Pucheng Cui, Tiancun Liu, Chaofei Guo, Xiaojie Yin

Published in

Nanoscale. Jul 16, 2026. Epub Jul 16, 2026.

Abstract

In this study, a Cu-HHTP/FeO(OH) composite material was successfully synthesized by incorporating uniquely structured FeO(OH) fabricated via a template-directed method into the self-assembly process of Cu-HHTP. The Cu-HHTP/FeO(OH) composite demonstrated a hexagonal-petal shape with Cu-HHTP nanoparticles uniformly attached to the surface of FeO(OH). The two components are interconnected via C-O-Fe bonds and form a heterojunction structure, which results in a narrow band gap (1.80 eV) compared to the individual components. This enhanced structure improves light utilization and facilitates the separation of photogenerated charges. Furthermore, the conductive MOF material Cu-HHTP promotes the transport of photogenerated charges and optimizes reaction kinetics. These features endow the Cu-HHTP/FeO(OH) composite with significantly improved photoelectrochemical properties. The Cu-HHTP/FeO(OH) composite demonstrated significantly enhanced photocatalytic activity, achieving methyl orange (MO) decolorization rates and rate constants, which are 1.4-17.4 times higher than those of its individual components. It also exhibited superior performance in rhodamine B (RhB) decolorization, further confirming the synergistic effect between Cu-HHTP and FeO(OH). Moreover, the Cu-HHTP/FeO(OH) heterojunction also exhibited remarkable electrochemical performance as an anode for lithium-ion batteries. The results demonstrated that this heterojunction composite material exhibited versatility and possessed great application potential in photocatalysis and lithium-ion batteries.

PMID:
42460489
Bibliographic data and abstract were imported from PubMed on 16 Jul 2026.

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