Beyond phosphines: phosphine-free manganese catalysts for the green generation and shuttling of hydrogen for sustainable transformation.

Authors

Rahul Sharma, Kailash Mohar, Avijit Mondal, Dipankar Srimani

Published in

Chemical communications (Cambridge, England). Aug 28, 2026. Epub Aug 28, 2026.

Abstract

This review highlights recent progress in manganese-catalyzed (de)hydrogenative reactions and hydrogenation related transformations, emphasizing air-stable, non-phosphine ligand frameworks as sustainable alternatives to traditional phosphine-based systems. It discusses structure-activity relationships and mechanistic features, while critically addressing divergent selectivity control as a key challenge and opportunity, along with broader future directions in sustainable manganese catalysis.

PMID:
42663133
Bibliographic data and abstract were imported from PubMed on 28 Aug 2026.

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