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Three-Dimensional Gelatin-Based Hydrogel Degradation and Cell Control by Two-Photon Excitation.

Created on 04 Sep 2026

Authors

Chisato Handa, Shoma Miura, Noemi Bata Hikuma, Reira Ishige, Taichi Urasaki, Shogo Oishi, Yuki Hatta, Hiroki Miyajima, Masaru Mukai, Shoji Maruo, Kazutoshi Iijima

Published in

ACS biomaterials science & engineering. Sep 02, 2026. Epub Sep 02, 2026.

Abstract

Light-responsive hydrogel-based cell scaffolds enable noninvasive, high-precision microenvironmental editing through light stimulation. Two-photon excitation using near-infrared lasers has recently gained attention as a less cytotoxic light irradiation method for cells. Two-photon excitation is an optical phenomenon that generates a localized high-energy state through the simultaneous absorption of two long-wavelength photons, enabling precise manipulation at the single-cell level, even within thick gels. In this study, photodegradable gelatin acrylate (Gelatin-PDA) hydrogels incorporating o-nitrobenzylacrylate (PDA) photodegradation units into a gelatin scaffold were degraded via two-photon excitation. Upon light irradiation, the Gelatin-PDA hydrogel was degraded, loosening its network. We demonstrated that it can be precisely decomposed into both two-dimensional and three-dimensional patterns. By light-irradiating the surface and interior of the Gelatin-PDA hydrogel, we controlled the human bone marrow-derived mesenchymal stem cell (hBM-MSC) orientation along the pattern and mouse embryonic fibroblast (NIH3T3) spheroid elongation. In this study, we achieved the dynamic and precise control of the cell elongation direction within a three-dimensional cell scaffold by combining a Gelatin-PDA hydrogel with advanced two-photon excitation technology. This contributes significantly to complex and dynamic biological tissue mimicry and paves the way for advances in regenerative medicine.

PMID:
42690902
Bibliographic data and abstract were imported from PubMed on 04 Sep 2026.

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