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Phase separation switches the protonation equilibrium in an ionic liquid aqueous solution.

Created on 09 Sep 2026

Authors

Moe Akazawa, Yasuyuki Tsuboi, Ken-Ichi Yuyama

Published in

Chemical communications (Cambridge, England). Sep 09, 2026. Epub Sep 09, 2026.

Abstract

Liquid-liquid phase separation of an ionic liquid/water mixture generates a microdroplet that switches the protonation equilibrium. Protonation is induced upon droplet formation by optical tweezing. The equilibrium shifts back toward deprotonation as the droplet grows and its composition changes. This work demonstrates the phase-separated droplet as an optically tunable microreactor.

PMID:
42714350
Bibliographic data and abstract were imported from PubMed on 09 Sep 2026.

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