Facile C-N bond construction from a molecular model of iron on silica.

Authors

Dylan R Bodner, Yuriko H Fujisato, Dolores L Ross, Jess Fletcher, Christine M Thomas, Paul M Zimmerman, Joshua A Buss

Published in

Chemical communications (Cambridge, England). Sep 14, 2026. Epub Sep 14, 2026.

Abstract

A dinuclear iron(II) complex supported by a bidentate amide ligand is used as a surrogate to study potential intermediates for C-H oxidation mediated by iron on silica. Both oxygen and organic azides react with the molecular complex to yield insertion products, the latter furnishing sterically encumbered secondary amines under uniquely mild conditions.

PMID:
42734048
Bibliographic data and abstract were imported from PubMed on 14 Sep 2026.

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