The return of C₂N₁₄: a new structural isomer of azidoazide azide.

Authors

Lukas J Eberhardt, Shouei Yiu, Jennifer Heidrich, Jörg Stierstorfer, Thomas M Klapötke

Published in

Chemical communications (Cambridge, England). Oct 03, 2026. Epub Oct 03, 2026.

Abstract

C₂N₁₄ (1-diazidocarbamoyl-5-azidotetrazole, "azidoazide azide") is one of the most famous energetic compounds owing to its extraordinary nitrogen content and extreme sensitivity. Herein, we report the synthesis and comprehensive characterization of its previously unknown constitutional isomer, 5-azido-2-diazidocarbamoyltetrazole (C₂N₁₄, 3) by single crystal X-ray diffraction, ¹³C, ¹⁴N NMR and IR spectroscopy.

PMID:
42826991
Bibliographic data and abstract were imported from PubMed on 03 Oct 2026.

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