Authors
Renqiang Huang, Le Dou, Yuangao Wang, Yu Luo, Li Xing, Ziqi Zhou, Wei Yu, Zhengxing Qin, Yurou Song, Kongyuan Zhang, Wenjuan Yan, Xin Jin, Chaohe Yang
Published in
Inorganic chemistry. Volume 65. Issue 41. Pages 24395-24409. Oct 19, 2026.
Abstract
Solid-state ion exchange (SSIE) method generates minimal wastewater and provides high ion-exchange rates, making it an emerging strategy for tuning zeolitic structures and properties. However, the mechanistic understanding involving ionic diffusion in zeolites remains unclear. In this work, we used Y zeolite as the proof-of-concept case, demonstrating that FeY catalysts prepared via the SSIE method exhibit superior catalytic activity for ketalization of glycerol and cyclohexanone. As one of the key findings, SSIE induces significantly less structural damage to the zeolite framework than ion exchange in liquid medium, where Fe3+ unusually migrates from supercages to β cages in the solid state. Na+ species associated with AlO4 tetrahedra are replaced by Fe3+, forming isolated Fe3+ and oligomeric FexOy species that correspond to [Fe(OH)2]+ and [HO-Fe-O-Fe-OH]2+. Consequently, the introduction of Fe3+ also modulates Lewis acidity, more importantly, generating additional Brønsted acid sites. Isolated Fe3+ species are favorably formulated during solid-state diffusion. Computational studies further reveal that the acidic hydroxyl groups associated with isolated Fe3+ species are the intrinsic active sites for glycerol ketalization. The mechanistic insights provide both experimental and theoretical foundations for designing next-generation zeolite catalysts for the green synthesis of bio-based specialty chemicals.
PMID:
42895386
Bibliographic data and abstract were imported from PubMed on 19 Oct 2026.
Read full publication at:
Please sign in
to see all details.
Advertisement
Stats
- Recommendations n/a n/a positive of 0 vote(s)
- Views 5
- Comments 0